Reduced-order model based active disturbance rejection control of hydraulic servo system with singular value perturbation theory

Hydraulic servomechanism is the typical mechanical/hydraulic double-dynamics coupling system with the high stiffness control and mismatched uncertainties input problems, which hinder direct applications of many advanced control approaches in the hydraulic servo fields. In this paper, by introducing the singular value perturbation theory, the original double-dynamics coupling model of the hydraulic servomechanism was reduced to a integral chain system. So that, the popular ADRC (active disturbance rejection control) technology could be directly applied to the reduced system. In addition, the high stiffness control and mismatched uncertainties input problems are avoided. The validity of the simplified model is analyzed and proven theoretically. The standard linear ADRC algorithm is then developed based on the obtained reduced-order model. Extensive comparative co-simulations and experiments are carried out to illustrate the effectiveness of the proposed method.     

The reversible hydrogen storage abilities of metal Na (Li,K, Ca,Mg, Sc,Ti, Y) decorated all-boron cage B28

The density functional theory is used to study the hydrogen storage abilities of alkali metal Li (Na, K), alkaline-earth metal Mg (Ca), and transition metal Ti (Ti, Sc, Y) decorated B₂₈, which is the possible smallest all-boron cage and contains one hexagonal hole and two octagonal holes. The most stable structure of B₂₈ explored by the calypso search is as same as that explored by Zhao et al. [Nanoscale 7(2015)15086]. It is calculated that the hollow sites outside of the cavities should be the most stable for all metals except for Ti. The average adsorption energy of H₂ molecules (E_ad) adsorbed by each Na (Ca, K, Mg, Sc, Y and Li) atom outside of the B₂₈ cage are in the range from 0.2 to 0.6 eV, which is suitable for hydrogen storage under near-ambient conditions. However, the largest hydrogen gravimetric density (HGD) for the B₂₈Sc₃-12H₂ structure is smaller than the target of 5.5 wt% by the year 2017 specified by the US Department of Energy (DOE). Therefore, the metal Ti (Sc) decorated all-boron cage B₂₈ should not be good candidates for hydrogen storage. The calculated desorption temperature and the molecular dynamic simulation indicate that the B₂₈M₃-nH₂ (M = Na, Li, Ca, K, Mg, Y) structures are easy to desorb the H₂ molecules at the room temperature (T = 300 k). Furthermore, the B₂₈ cages bridged by the sp²-terminated B₅ chain can hold Na (Li, Ca, K, Mg, Y) atoms to capture hydrogen molecules with moderate E_ad and HGD. These findings suggest a new route to design hydrogen storage materials under the near-ambient conditions.     

一种基于信息扩散理论的降雨空间插值方法

根据有限的雨量站观测资料进行空间插值是获取精确降雨空间分布信息的有效手段,基于信息扩散理论,建立了一种降雨量空间插值方法,并分别采用窗宽经验公式法、最优窗宽迭代法和粒子群优化3种算法对信息扩散函数中窗宽这一关键参数进行估计。以浙江省临安市雨量站月降雨量的插值计算为例,将3种算法应用于月降雨量资料的插值计算中,并将其插值效果与普通克里金方法进行比较。结果表明,使用粒子群优化算法估计窗宽参数的信息扩散函数插值方法显著优于其他方法,经验公式估计窗宽参数的信息扩散函数插值方法与普通克里金方法插值效果相当,使用最优窗宽迭代估计窗宽参数的信息扩散函数插值效果最差。     

Photoelectrochemical analysis of band gap modulated TiO2 for photocatalytic water splitting

In this study the photocatalysis efficiency of titania (TiO₂) is increased by conjugating it with folic acid (FA) molecules through a silane linker (APTMS) layer. Electrochemical testing demonstrated higher negative open circuit potential (OCP) in surface engineered TiO₂ as compared to TiO₂ indicating higher Schottky barrier leading to suppressed electron–hole pair recombination. The photocurrent density under no bias conditions demonstrated 55% increase in modified titania due to lower band gap and suppressed electron hole pair recombination. The mechanism behind higher photocatalytic properties of surface engineered TiO₂ was derived using density functional theory (DFT).     

Analogy between adsorption and sorption:An elementary mechanistic approach.I.Monolayer adsorption and sorption without solvent cluster formation

The elementary mechanistic model of adsorption and sorption is based on a simple hypothesis:the adsorption sites are uniformly distributed on the surface of the pore walls in the adsorbent,the sorption sites are uniformly distributed in the volume of the polymer.In this first paper we will analyze the simple case where one solute mol-ecule is only allowed to occupy a single adsorption or sorption site.A common elementary occupation law of the free sites is assumed:the differential increase of the number of the adsorbed/sorbed molecules is proportional to the differential increase of the activity of the solute and the concentration of the free(non-occupied)sites in the solid.The proportionality coefficient is called affinity coefficient depending on the solid/solute couple and on the temperature and independent of the concentration of the solute.In adsorption the concentration of the free sites is a surface concentration on the pore walls and in sorption it is expressed by the molarity.The simple mono-layer adsorption law of Jovanovi?is obtained:n=n0(1?e?KP)where n is the number of moles adsorbed when the pressure is P. n0is the total number of adsorption sites and K the affinity coefficient for adsorption.The sorption law writes:a= 1k? ?1??]+1?rk ln?1+1r?1??]where?,r and k hold respectively for the volume fraction of the solvent in the polymer,for the ratio of the molar volumes of the solvent to the elementary polymer chain containing one single adsorption site and for the sorption affinity coefficient.The confrontation of these equations to experimental isotherms is satisfactory in comparison with the classical Langmuir and Flory-Huggins equations:the best results are obtained for adsorption of vapors on a 5A zeolite and for all analyzed sorption results.     

Volume-based method for spectrum sensing

It is recently shown that algorithms derived from random matrix theory (RMT) can provide superior performance for spectrum sensing, which corresponds to the task of detecting the presence of primary users in cognitive radio. The essence of the RMT-based methods is to utilize the distribution of extremal eigenvalues of the received signal sample covariance matrix (SCM), namely, the Tracy–Widom (TW) distribution. Although the TW distribution is quite useful in spectrum sensing, computationally demanding numerical evaluation is required because it does not have an explicit closed-form expression. In this paper, we devise two novel volume-based detectors by exploiting the determinant of the SCM or volume to distinguish between the signal-presence and signal-absence cases. With the use of RMT, we accurately produce the theoretical decision threshold for one of the detectors under the Gaussian noise assumption. Simulation results are included to illustrate the effectiveness of the volume-based detectors.     

Robust user equilibrium model based on cumulative prospect theory under distribution-free travel time

The assumption widely used in the user equilibrium model for stochastic network was that the probability distributions of the travel time were known explicitly by travelers. However, this distribution may be unavailable in reality. By relaxing the restrictive assumption, a robust user equilibrium model based on cumulative prospect theory under distribution-free travel time was presented. In the absence of the cumulative distribution function of the travel time, the exact cumulative prospect value(CPV) for each route cannot be obtained. However, the upper and lower bounds on the CPV can be calculated by probability inequalities.Travelers were assumed to choose the routes with the best worst-case CPVs. The proposed model was formulated as a variational inequality problem and solved via a heuristic solution algorithm. A numerical example was also provided to illustrate the application of the proposed model and the efficiency of the solution algorithm.     

基于期权合约的战备物资储备激励机制研究

针对通用战备物资依托企业合同储备问题,从合作博弈的角度出发,引入期权合约理论,构建期权合约下合同储备激励机制模型。分析影响各方博弈主体策略选择的因素,对不同策略下参与主体双方的利润期望进行比较分析,确立期权合约理论下合理的期权价格范围,寻求军地双赢策略。实例分析表明,提出的方法具有可行性和有效性。     

Hybrid GA for material routing optimization in supply chain

In designing a supply chain (SC) system, the problem arises when a company has unsatisfactory inventory control policy and material routing between supplier–producer and distributor in SC considering specified cost and demand. The integration of decisions of different functions into a single optimization model is the base of this research. The aim of this paper is to study and compare the existing models of supply, production and distribution in SC and propose a model which integrates mentioned criteria in supply chain management (SCM). Furthermore, it proposes a new method for calculation of fitness function in genetic algorithm (GA) process. The successful designing of this model has led us to explore the use of heuristic methods such as GA to quantify the flow of SC, information and material flow. At first, fuzzy analytic hierarchy process (FAHP) is adapted to evaluate objective function weights in SC. Then final weights of objective function are determined by the technique for order of preference by similarity to ideal solution (TOPSIS). This research also simulated the real company SC operations, and determines the most effective strategic and operational policies for an effective SC system. The result obtained from the model shows that it is robust. This model can also be applied to other industrial environments with slight modifications.